Setup, showing the slit below, with the spark gap behind it and the diffraction spectrum floating above in air

A Cokin P040 diffraction grating (240 lines per mm) was simply placed in front of a DSLR lense (5 Euros only, I was lucky, 40 Euros is a typical price), resulting in the following image:

Spectrum of the air-gap flash

Since air consists of 80% Nitrogen, 20% Oxygen and a small fraction of Argon, it’s spectrum should be a mix of the spectra of these atoms (some simulated spectra here). But when I look at this spectrum, I find it hard to match them. Also it lacks any hint of yellow tones, to me it is just RG&B.

For comparison I have also imaged my Nikon SB-600. I would expect a spectrum similar to Xenon, but also that does not really look like it.

Nikon SB-600 spectrum

For reference, these are the spectra from Joachim Koppen’s website (http://astro.u-strasbg.fr/~koppen/).

Nitrogen spectrum (78% of air)

Oxygen spectrum (21% of air)

Argon (1% of air)

Finally an attempt to match the spectra of the air-gap flash to Oxygen and Nitrogen. It seems that the spectrum mainly consists of Nitrogen (which was to be expected). The simulated spectra of Oxygen en Nitrogen were blurred to match the resolution of the grating/slit photo.

Spectra of Oxygen and Nitrogen (simulated) together with the grating result for the air-gap flash.